Explain radioactive half-life and its role in radiometric dating; Calculate radioactive half-life and solve problems associated with radiometric dating. Dating rocks by these radioactive timekeepers is simple in theory, but the Potassium is found in most rock-forming minerals, the half-life of its. The half-lives of many radioactive isotopes have been how decay and half life work to enable radiometric dating.
Lastly, accuracy of C dating has been affected by atmosphere nuclear weapons testing. Fission bombs ignite to produce more C artificially. Samples tested during and after this period must be checked against another method of dating isotopic or tree rings.
To calculate the age of a substance using isotopic dating, use the equation below: Ra has a half-life of years. Radioactive Dating Using Nuclides Other than Carbon Radioactive dating can also use other radioactive nuclides with longer half-lives to date older events.
For example, uranium which decays in a series of steps into lead can be used for establishing the age of rocks and the approximate age of the oldest rocks on earth. Since U has a half-life of 4.
In a sample of rock that does not contain appreciable amounts of Pb, the most abundant isotope of lead, we can assume that lead was not present when the rock was formed. Therefore, by measuring and analyzing the ratio of U Pb, we can determine the age of the rock. This assumes that all of the lead present came from the decay of uranium If there is additional lead present, which is indicated by the presence of other lead isotopes in the sample, it is necessary to make an adjustment.
Potassium-argon dating uses a similar method. K decays by positron emission and electron capture to form Ar with a half-life of 1. If a rock sample is crushed and the amount of Ar gas that escapes is measured, determination of the Ar K ratio yields the age of the rock. Other methods, such as rubidium-strontium dating Rb decays into Sr with a half-life of As ofthe oldest known rocks on earth are the Jack Hills zircons from Australia, found by uranium-lead dating to be almost 4.
An ingenious application of half-life studies established a new science of determining ages of materials by half-life calculations. After one half-life, a 1. Present day estimates for the age of the Earth's crust from this method is at 4 billion years. Isotopes with shorter half-lives are used to date more recent samples.
Chemists and geologists use tritium dating to determine the age of water ocean and fresh. In addition, tritium dating can be useful in determining the age of wines and brandies. Summary and Vocabulary The half-life of an isotope is used to describe the rate at which the isotope will decay and give off radiation. Using the half-life, it is possible to predict the amount of radioactive material that will remain after a given amount of time.
Its half-life is approximately years. After an organism has been dead for 60, years, so little carbon is left that accurate dating cannot be established.
Calculating Half-Life - Chemistry LibreTexts
On the other hand, the concentration of carbon falls off so steeply that the age of relatively young remains can be determined precisely to within a few decades. Closure temperature If a material that selectively rejects the daughter nuclide is heated, any daughter nuclides that have been accumulated over time will be lost through diffusionsetting the isotopic "clock" to zero.
The temperature at which this happens is known as the closure temperature or blocking temperature and is specific to a particular material and isotopic system. These temperatures are experimentally determined in the lab by artificially resetting sample minerals using a high-temperature furnace. As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy. At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes.
This temperature is what is known as closure temperature and represents the temperature below which the mineral is a closed system to isotopes. Thus an igneous or metamorphic rock or melt, which is slowly cooling, does not begin to exhibit measurable radioactive decay until it cools below the closure temperature. The age that can be calculated by radiometric dating is thus the time at which the rock or mineral cooled to closure temperature.
This field is known as thermochronology or thermochronometry. The age is calculated from the slope of the isochron line and the original composition from the intercept of the isochron with the y-axis. The equation is most conveniently expressed in terms of the measured quantity N t rather than the constant initial value No. The above equation makes use of information on the composition of parent and daughter isotopes at the time the material being tested cooled below its closure temperature.
This is well-established for most isotopic systems. Plotting an isochron is used to solve the age equation graphically and calculate the age of the sample and the original composition. Modern dating methods[ edit ] Radiometric dating has been carried out since when it was invented by Ernest Rutherford as a method by which one might determine the age of the Earth.
In the century since then the techniques have been greatly improved and expanded. The mass spectrometer was invented in the s and began to be used in radiometric dating in the s. It operates by generating a beam of ionized atoms from the sample under test. The ions then travel through a magnetic field, which diverts them into different sampling sensors, known as " Faraday cups ", depending on their mass and level of ionization.
- Radiometric dating
On impact in the cups, the ions set up a very weak current that can be measured to determine the rate of impacts and the relative concentrations of different atoms in the beams. Uranium—lead dating method[ edit ] Main article: Uranium—lead dating A concordia diagram as used in uranium—lead datingwith data from the Pfunze BeltZimbabwe. This scheme has been refined to the point that the error margin in dates of rocks can be as low as less than two million years in two-and-a-half billion years.
Zircon has a very high closure temperature, is resistant to mechanical weathering and is very chemically inert.
Zircon also forms multiple crystal layers during metamorphic events, which each may record an isotopic age of the event. This can be seen in the concordia diagram, where the samples plot along an errorchron straight line which intersects the concordia curve at the age of the sample.
Samarium—neodymium dating method[ edit ] Main article: Samarium—neodymium dating This involves the alpha decay of Sm to Nd with a half-life of 1. Accuracy levels of within twenty million years in ages of two-and-a-half billion years are achievable. Potassium—argon dating This involves electron capture or positron decay of potassium to argon Potassium has a half-life of 1.
Rubidium—strontium dating method[ edit ] Main article: Rubidium—strontium dating This is based on the beta decay of rubidium to strontiumwith a half-life of 50 billion years. This scheme is used to date old igneous and metamorphic rocksand has also been used to date lunar samples. Closure temperatures are so high that they are not a concern.
Rubidium-strontium dating is not as precise as the uranium-lead method, with errors of 30 to 50 million years for a 3-billion-year-old sample. Uranium—thorium dating method[ edit ] Main article: Uranium—thorium dating A relatively short-range dating technique is based on the decay of uranium into thorium, a substance with a half-life of about 80, years.
It is accompanied by a sister process, in which uranium decays into protactinium, which has a half-life of 32, years. While uranium is water-soluble, thorium and protactinium are not, and so they are selectively precipitated into ocean-floor sedimentsfrom which their ratios are measured.
5.7: Calculating Half-Life
The scheme has a range of several hundred thousand years. A related method is ionium—thorium datingwhich measures the ratio of ionium thorium to thorium in ocean sediment.
Radiocarbon dating method[ edit ] Main article: Carbon is a radioactive isotope of carbon, with a half-life of 5, years,   which is very short compared with the above isotopes and decays into nitrogen. Carbon, though, is continuously created through collisions of neutrons generated by cosmic rays with nitrogen in the upper atmosphere and thus remains at a near-constant level on Earth. The carbon ends up as a trace component in atmospheric carbon dioxide CO2.
A carbon-based life form acquires carbon during its lifetime. Plants acquire it through photosynthesisand animals acquire it from consumption of plants and other animals. When an organism dies, it ceases to take in new carbon, and the existing isotope decays with a characteristic half-life years. The proportion of carbon left when the remains of the organism are examined provides an indication of the time elapsed since its death.
This makes carbon an ideal dating method to date the age of bones or the remains of an organism. The carbon dating limit lies around 58, to 62, years.